This question was closed without grading. Reason: Answer found elsewhere
Apr 20, 2022 09:07
2 yrs ago
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French term
corps considérés
French to English
Science
Chemistry; Chem Sci/Eng
from an atlas of electrochemical equilibriums
1. CORPS CONSIDÉRÉS ET CORPS NON CONSIDÉRÉS.
Nombres
d'oxydation
(Z). Considérés. Non
considérés. µ° (cal.). Dénominations, couleurs, systèmes cristallins.
Nombres
d'oxydation
(Z). Considérés. Non
considérés. µ° (cal.). Dénominations, couleurs, systèmes cristallins.
Proposed translations
(English)
| 3 +2 | species considered |
Bourth
|
Proposed translations
+2
39 mins
species considered
An interpretation framework is presented which provides a straightforward means to characterise the electrochemical reactivity of aqueous ions together with their various hydrolysed counterparts. Our novel approach bypasses the more laborious strategy of solving rigorously, for all RELEVANT SPECIES, the complete set of Butler Volmer equations coupled to diffusion differential equations
https://hal.univ-lorraine.fr/hal-02941348/document
(by one Raewyn Town, along with French and Dutch-sounding names)
We demonstrate their use in scanning electrochemical microscopy (SECM) experiments wherein the SPECIES OF INTEREST (up to 2-electron reduction or 4-electron oxidation from the native charge-state of the MPCs) is generated at the tip electrode, providing a simple means to adjust the driving force of the electron transfer (ET).
https://pubs.acs.org/doi/pdf/10.1021/ja0282137
It must be mentioned that performing such evaluating protocols requires initially performing accurate DFT-based geometry optimizations for all SPECIES THAT ARE INVOLVED in the electrochemical reduction and catalytic cycle of interest. [...]for the electrochemical reduction and the consequent protonation of the [η5-Cp*] ligand to form [η4-Cp*H] of the redox active SPECIES considered in this study.
https://www.nature.com/articles/s41598-020-62758-6
This original substrate preparation allowed to perform electrochemical measurements on ionized SPECIES in solution with decreasing concentration down to 10−7 molar. [...]Considering that the Brownian coefficient of diffusion is inversely related to the hydrodynamic diameter of a diffusing molecule, different species in a solution, with different sizes and thus mobilities, would behave differently upon the application of the same stimulus, and this is the case of the SPECIES CONSIDERED here for the analysis.
https://www.hindawi.com/journals/bmri/2014/302694/
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Note added at 56 mins (2022-04-20 10:04:23 GMT)
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Medium confidence only because French seems to break 'espèces' down into 'corps purs' and 'corps mixtes' (or 'composés'). I have found no such change in terminology in English, just 'pure species' and 'mixed species', but I cannot exlude the possibility of there being another word for these subsets also.
https://hal.univ-lorraine.fr/hal-02941348/document
(by one Raewyn Town, along with French and Dutch-sounding names)
We demonstrate their use in scanning electrochemical microscopy (SECM) experiments wherein the SPECIES OF INTEREST (up to 2-electron reduction or 4-electron oxidation from the native charge-state of the MPCs) is generated at the tip electrode, providing a simple means to adjust the driving force of the electron transfer (ET).
https://pubs.acs.org/doi/pdf/10.1021/ja0282137
It must be mentioned that performing such evaluating protocols requires initially performing accurate DFT-based geometry optimizations for all SPECIES THAT ARE INVOLVED in the electrochemical reduction and catalytic cycle of interest. [...]for the electrochemical reduction and the consequent protonation of the [η5-Cp*] ligand to form [η4-Cp*H] of the redox active SPECIES considered in this study.
https://www.nature.com/articles/s41598-020-62758-6
This original substrate preparation allowed to perform electrochemical measurements on ionized SPECIES in solution with decreasing concentration down to 10−7 molar. [...]Considering that the Brownian coefficient of diffusion is inversely related to the hydrodynamic diameter of a diffusing molecule, different species in a solution, with different sizes and thus mobilities, would behave differently upon the application of the same stimulus, and this is the case of the SPECIES CONSIDERED here for the analysis.
https://www.hindawi.com/journals/bmri/2014/302694/
--------------------------------------------------
Note added at 56 mins (2022-04-20 10:04:23 GMT)
--------------------------------------------------
Medium confidence only because French seems to break 'espèces' down into 'corps purs' and 'corps mixtes' (or 'composés'). I have found no such change in terminology in English, just 'pure species' and 'mixed species', but I cannot exlude the possibility of there being another word for these subsets also.
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